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  Vibrational enhancement of electron emission in CO (a3Π) quenching at a clean metal surface

Grätz, F., Engelhardt, D., Wagner, R. J. V., Haak, H., Meijer, G., Wodtke, A. M., et al. (2013). Vibrational enhancement of electron emission in CO (a3Π) quenching at a clean metal surface. Physical Chemistry Chemical Physics, 15(36), 14951-14955. doi:10.1039/C3CP52468J.

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 Creators:
Grätz, Fabian1, 2, 3, Author           
Engelhardt, Daniel2, 3, Author
Wagner, Roman J V2, 3, Author
Haak, Henrik1, Author           
Meijer, Gerard1, Author           
Wodtke, Alec M2, 3, Author
Schaefer , Tim2, 3, Author
Affiliations:
1Molecular Physics, Fritz Haber Institute, Max Planck Society, ou_634545              
2Georg-August-Universität Göttingen, Institut für Physikalische Chemie, Tammannstr. 6, 37077 Göttingen, Germany , ou_persistent22              
3Max-Planck-Institut Für Biophysikalische Chemie, Karl Friedrich-Bonhoeffer-Institut, Am Fassberg 11, 37077 Göttingen, Germany, ou_persistent22              

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 Abstract: We have combined a Stark decelerator with a molecular beam-surface scattering setup to accurately measure the absolute electron emission yield, γ, of CO (a3Π) quenching at a Au(111) surface with quantum state resolution. We clearly observe an enhanced probability of electron emission when scattering vibrationally excited states of CO from the surface.

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Language(s): eng - English
 Dates: 2013-06-132013-07-172013-07-192013-09-28
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/C3CP52468J
 Degree: -

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Title: Physical Chemistry Chemical Physics
Source Genre: Journal
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Publ. Info: Cambridge [England] : Royal Society of Chemistry
Pages: - Volume / Issue: 15 (36) Sequence Number: - Start / End Page: 14951 - 14955 Identifier: ISSN: 1463-9076
CoNE: https://pure.mpg.de/cone/journals/resource/954925272413_1