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  Fluorescence screening of tartaric acid-derived azamacrocycles synthesized via sequential hydroformylation/reductive amination as potential ligands for asymmetric catalysis

Angelovski, G., Keränen, M., & Eilbracht, P. (2005). Fluorescence screening of tartaric acid-derived azamacrocycles synthesized via sequential hydroformylation/reductive amination as potential ligands for asymmetric catalysis. Tetrahedron: Asymmetry, 16, 1919-1926.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0013-D6A9-9 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0013-D6AA-7
Genre: Journal Article

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Angelovski, G1, Author           
Keränen, MD, Author
Eilbracht, P, Author
Affiliations:
1Department Physiology of Cognitive Processes, Max Planck Institute for Biological Cybernetics, Max Planck Society, ou_1497798              

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 Abstract: Azamacrocyclic fluorophores containing piperazine units were synthesized using sequential rhodium-catalyzed regioselective hyd Azamacrocycles containing a tartaric acid-derived unit and aryl units were synthesized via rhodium-catalyzed hydroformylation and subsequent reductive amination in a tandem or stepwise fashion. Upon fluorescence emission experiments, some of the macrocycles showed chelating affinities towards transition metals such as zinc or rhodium.

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 Dates: 2005
 Publication Status: Issued
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 Rev. Type: -
 Identifiers: BibTex Citekey: 3342
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Title: Tetrahedron: Asymmetry
Source Genre: Journal
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Pages: - Volume / Issue: 16 Sequence Number: - Start / End Page: 1919 - 1926 Identifier: -