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  Experimental determination of single solute and competitive adsorption isotherms

Seidel-Morgenstern, A. (2004). Experimental determination of single solute and competitive adsorption isotherms. Journal of Chromatography A, 1037, 255-272. doi:10.1016/j.chroma.2003.11.108.

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Seidel-Morgenstern, A.1, 2, Autor           
Affiliations:
1Physical and Chemical Foundations of Process Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society, ou_1738150              
2Otto-von-Guericke-Universität Magdeburg, External Organizations, ou_1738156              

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 Zusammenfassung: In order to design and to optimise preparative liquid chromatography, the knowledge of the underlying thermodynamic functions, i.e. the adsorption isotherms, is of large importance. Usually these functions can not be predicted and various techniques have been suggested to determine them experimentally. In this paper, several important methods to measure adsorption equilibrium data are discussed and evaluated. The main focus is set on dynamic methods analysing concentration profiles that could be detected at the outlet of fixed-beds packed with the stationary phase of interest. The theoretical background of the different methods is explained using classical equilibrium theory and the equilibrium dispersion model. Each method is illustrated based on experimental data collected in our laboratory. Based on these personal experiences recommendations are given regarding the potential and the applicability of the methods discussed. © 2003 Elsevier B.V. All rights reserved. [accessed 2013 November 27th]

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Sprache(n): eng - English
 Datum: 2004
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: -
 Identifikatoren: eDoc: 207951
Anderer: 54/04
DOI: 10.1016/j.chroma.2003.11.108
 Art des Abschluß: -

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Titel: Journal of Chromatography A
Genre der Quelle: Zeitschrift
 Urheber:
Affiliations:
Ort, Verlag, Ausgabe: Amsterdam : Elsevier
Seiten: - Band / Heft: 1037 Artikelnummer: - Start- / Endseite: 255 - 272 Identifikator: ISSN: 0021-9673
CoNE: https://pure.mpg.de/cone/journals/resource/954925527837_1