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  Optimal Process Design for the Synthesis of 2,3-Dimethylbutene-1

Gangadwala, J., Kienle, A., Haus, U.-U., Michaels, D., & Weismantel, R. (2005). Optimal Process Design for the Synthesis of 2,3-Dimethylbutene-1. In L. Puigjaner, & A. Espuña (Eds.), European Symposium on Computer Aided Process Engineering - 15 (pp. 847-852). Amsterdam: Elsevier.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0013-9CA2-B Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-F318-F
Genre: Conference Paper

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 Creators:
Gangadwala, J.1, Author           
Kienle, A.1, 2, Author           
Haus, U.-U.2, Author
Michaels, D.2, Author
Weismantel, R.2, Author
Affiliations:
1Process Synthesis and Process Dynamics, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society, ou_1738153              
2Otto-von-Guericke-Universität Magdeburg, External Organizations, ou_1738156              

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Free keywords: Reactive distillation; isomerization; 2,3-dimethylbutenes; optimization; MINLP
 Abstract: This paper is concerned with the computer-aided optimal design of reaction-distillation processes. The production of solvent 2,3-dimethylbutene-1 by isomerization of 2,3-dimethylbutene-2 is considered as an innovative benchmark problem. Possible process candidates are a reactive distillation column, a reactor coupled to a nonreactive distillation column or a reactive reboiler with a nonreactive distillation column on top. Local MINLP optimization indicates that the reactive distillation has the lowest total annualized costs. However, due to the non-convexity of the underlying mathematical problem better solutions for the other process candidates cannot be excluded. For this purpose a new global approach is proposed which is based on discrete optimization of the underlying model equations and which proves globally that reactive distillation is the best option. © 2005 Elsevier B.V. All rights reserved. [accessed 2014 January 10th]

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Language(s): eng - English
 Dates: 2005
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: eDoc: 223751
DOI: 10.1016/S1570-7946(05)80263-9
 Degree: -

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Title: 15th European Symposium on Computer Aided Process Engineering - ESCAPE
Place of Event: Barcelona, Spain
Start-/End Date: 2005-05-29 - 2005-06-01

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Title: European Symposium on Computer Aided Process Engineering - 15
Source Genre: Proceedings
 Creator(s):
Puigjaner, L., Editor
Espuña, A., Editor
Affiliations:
-
Publ. Info: Amsterdam : Elsevier
Pages: - Volume / Issue: - Sequence Number: - Start / End Page: 847 - 852 Identifier: -

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Title: Computer Aided Chemical Engineering
Source Genre: Series
 Creator(s):
Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 20 C Sequence Number: - Start / End Page: - Identifier: ISSN: 1570-7946