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  Solubility of Chiral Threonine Species in Water/Ethanol Mixtures

Sapoundjiev, D., Lorenz, H., & Seidel-Morgenstern, A. (2006). Solubility of Chiral Threonine Species in Water/Ethanol Mixtures. Journal of Chemical and Engineering Data, 51(5), 1562-1566. doi:10.1021/je060053h.

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Sapoundjiev, D.1, 2, Autor           
Lorenz, H.1, Autor           
Seidel-Morgenstern, A.1, 2, Autor           
Affiliations:
1Physical and Chemical Foundations of Process Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society, ou_1738150              
2Otto-von-Guericke-Universität Magdeburg, External Organizations, ou_1738156              

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 Zusammenfassung: Solubility equilibria of threonine in water/ethanol mixtures were measured in the temperature range between (10 and 46)°C. Threonine exhibits good solubility in water and is hardly soluble in ethanol. The ternary-phase diagram of the threonine enantiomers in the solvents used reveals the presence of a conglomerate-forming system. Threonine shows ideal solution behavior (i.e., heterochiral interactions do not occur in solution). To correlate the measured data with regard to temperature and solvent composition, a simple empirical approach is proposed. The correlation presented is of interest for calculation of solubilities when designing crystallization or chromatography-based processes to separate the threonine enantiomers. Copyright © 2006 American Chemical Society [accessed 2013 November 27th]

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Sprache(n): eng - English
 Datum: 2006
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
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 Art der Begutachtung: -
 Identifikatoren: eDoc: 290813
DOI: 10.1021/je060053h
Anderer: 30/06
 Art des Abschluß: -

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Titel: Journal of Chemical and Engineering Data
Genre der Quelle: Zeitschrift
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Ort, Verlag, Ausgabe: Washington : American Chemical Society
Seiten: - Band / Heft: 51 (5) Artikelnummer: - Start- / Endseite: 1562 - 1566 Identifikator: ISSN: 0021-9568
CoNE: https://pure.mpg.de/cone/journals/resource/991042728182784