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  The halogen bond made visible: experimental charge density of a very short intermolecular Cl•••Cl donor–acceptor contact

Wang, R., Dols, T., Lehmann, C. W., & Englert, U. (2012). The halogen bond made visible: experimental charge density of a very short intermolecular Cl•••Cl donor–acceptor contact. Chemical Communications, 48(54), 6830-6832. doi:10.1039/c2cc32647g.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000E-EC35-9 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-000E-EC36-7
Genre: Journal Article

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 Creators:
Wang, Ruimin1, Author
Dols, Thomas2, Author           
Lehmann, Christian W.2, Author           
Englert , Ulli1, Author
Affiliations:
1Rhein Westfal TH Aachen, Inst Inorgan Chem, Landoltweg 1, D-52074 Aachen, Germany, ou_persistent22              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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 Abstract: [ZnCl2(3,4,5-trichloropyridine)2] features short intermolecular Cl***Cl contacts between halogen atoms of different nature, and a charge density study provides experimental evidence for the accepted model of the halogen bonds: an arene-bonded Cl atom acts as a donor of electron density towards the “sigma hole” of a chlorido ligand attached to a neighbouring Zn(II) cation.

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 Dates: 2012
 Publication Status: Issued
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 Rev. Type: -
 Identifiers: DOI: 10.1039/c2cc32647g
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Title: Chemical Communications
  Other : Chem. Commun.
Source Genre: Journal
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Pages: - Volume / Issue: 48 (54) Sequence Number: - Start / End Page: 6830 - 6832 Identifier: ISSN: 1359-7345
CoNE: https://pure.mpg.de/cone/journals/resource/954928495413
DOI: 10.1039/c2cc32647g