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  Impact of rainfall and topography on the distribution of clays and major cations in granitic catenas of southern Africa

Khomo, L., Hartshorn, A. S., Rogers, K. H., & Chadwick, O. A. (2011). Impact of rainfall and topography on the distribution of clays and major cations in granitic catenas of southern Africa. Catena, 87(1), 119-128. doi:10.1016/j.catena.2011.05.017.

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Khomo, L.1, Author           
Hartshorn, A. S., Author
Rogers, K. H., Author
Chadwick, O. A., Author
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1Department Biogeochemical Processes, Prof. S. E. Trumbore, Max Planck Institute for Biogeochemistry, Max Planck Society, ou_1497752              

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Free keywords: Soil Arid/semi-arid/sub-humid rainfall Soil development Clay mineralogy Kruger National Park soils model
 Abstract: Soil catenas integrate and amplify gravity transfer and differentiation processes of eluviation and illuviation in soil profiles. We quantified differences in these redistribution processes along granitic catenas across an arid to sub-humid climate gradient in Kruger National Park, South Africa. We measured soil properties in nine catenas sampled from three areas receiving annual rainfall of 470 mm (arid zone), 550 mm (semi-arid zone) and 730 mm (sub-humid zone). As rainfall increased, kaolinite replaced smectite as the dominant clay mineral in all landscape positions across the catenas. Toeslopes showed the strongest evidence of this transition with an excess of smectite in the arid catenas but complete prevalence of kaolinite in toeslopes of sub-humid catenas. The concentration and distribution of clay along the catenas were dependent on landscape position as well - soil profiles at and near the crests were clay depleted (as low as 1%) while those at the toeslopes had much more clay (up to 60%). Clay redistribution along catenas was sensitive to climate with the least amount of redistribution occurring in the dry sites and the most occurring in the wet sites. As a consequence, the sub-humid catenas had clay accumulation only in a small part of the toeslopes while the bulk of their length was represented by highly leached soils. In contrast, arid zone catenas showed little clay redistribution and semi-arid sites displayed the greatest within-catena clay redistribution and preservation. Clay movement and storage conditioned other soil properties such as CEC, base cation distribution, base saturation and pH. (C) 2011 Elsevier B.V. All rights reserved.

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Language(s): eng - English
 Dates: 2011
 Publication Status: Issued
 Pages: -
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 Rev. Type: -
 Identifiers: DOI: 10.1016/j.catena.2011.05.017
ISI: ://WOS:000293105300013
Other: BGC1525
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Title: Catena
Source Genre: Journal
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Publ. Info: Amsterdam [etc.] : Elsevier
Pages: - Volume / Issue: 87 (1) Sequence Number: - Start / End Page: 119 - 128 Identifier: CoNE: https://pure.mpg.de/cone/journals/resource/954925519635
ISSN: 0341-8162