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  Sulfur isotope analysis of cinnabar from Roman wall paintings by elemental analysis/isotope ratio mass spectrometry – tracking the origin of archaeological red pigments and their authenticity

Spangenberg, J. E., Lavrič, J. V., Meisser, N., & Serneels, V. (2010). Sulfur isotope analysis of cinnabar from Roman wall paintings by elemental analysis/isotope ratio mass spectrometry – tracking the origin of archaeological red pigments and their authenticity. Rapid Communications in Mass Spectrometry, 24(19), 2812-2816. doi:10.1002/rcm.4705.

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Spangenberg, Jorge E., Author
Lavrič, J. V.1, Author           
Meisser, Nicolas, Author
Serneels, Vincent, Author
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1Tall Tower Atmospheric Gas Measurements, Dr. J. Lavrič, Department Biogeochemical Systems, Prof. M. Heimann, Max Planck Institute for Biogeochemistry, Max Planck Society, ou_1497786              

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 Abstract: Abstract The most valuable pigment of the Roman wall paintings was the red color obtained from powdered cinnabar (Minium Cinnabaris pigment), the red mercury sulfide (HgS), which was brought from mercury (Hg) deposits in the Roman Empire. To address the question of whether sulfur isotope signatures can serve as a rapid method to establish the provenance of the red pigment in Roman frescoes, we have measured the sulfur isotope composition (δ34S value in ‰ VCDT) in samples of wall painting from the Roman city Aventicum (Avenches, Vaud, Switzerland) and compared them with values from cinnabar from European mercury deposits (Almadén in Spain, Idria in Slovenia, Monte Amiata in Italy, Moschellandsberg in Germany, and Genepy in France). Our study shows that the δ34S values of cinnabar from the studied Roman wall paintings fall within or near to the composition of Almadén cinnabar; thus, the provenance of the raw material may be deduced. This approach may provide information on provenance and authenticity in archaeological, restoration and forensic studies of Roman and Greek frescoes. Copyright © 2010 John Wiley & Sons, Ltd.

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 Dates: 2010
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 Identifiers: DOI: 10.1002/rcm.4705
Other: BGC1442
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Title: Rapid Communications in Mass Spectrometry
Source Genre: Journal
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Publ. Info: New York, NY : John Wiley & Sons
Pages: - Volume / Issue: 24 (19) Sequence Number: - Start / End Page: 2812 - 2816 Identifier: CoNE: https://pure.mpg.de/cone/journals/resource/954925574961
ISSN: 1097-0231