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  Incipient chemical bond formation of Xe to a cationic silicon cluster: Vibrational spectroscopy and structure of the Si4Xe+ complex

Savoca, M., Langer, J., Harding, D. J., Dopfer, O., & Fielicke, A. (2013). Incipient chemical bond formation of Xe to a cationic silicon cluster: Vibrational spectroscopy and structure of the Si4Xe+ complex. Chemical Physics Letters, 557, 49-52. doi:10.1016/j.cplett.2012.12.020.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000E-95EB-2 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-000E-95EE-B
Genre: Journal Article

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Si4Xe_CPL.pdf (Any fulltext), 244KB
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https://hdl.handle.net/11858/00-001M-0000-000E-ACED-1
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2013
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North-Holland
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 Creators:
Savoca, Marco1, Author
Langer, Judith1, Author
Harding, Daniel J.2, Author           
Dopfer, Otto1, Author
Fielicke, André2, Author           
Affiliations:
1Institut für Optik und Atomare Physik, Technische Universität Berlin, Hardenbergstraße 36, 10623 Berlin, Germany, ou_persistent22              
2Molecular Physics, Fritz Haber Institute, Max Planck Society, ou_634545              

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 Abstract: The size-selective vibrational spectrum of Si4Xe+ in the 240–500 cm-1 range has been recorded using infrared (IR) multiple photon dissociation spectroscopy. Comparison to linear IR absorption spectra of Si4+ and Si4Xe+ calculated using density functional theory including dispersion corrections reveals an important influence of the Xe ligand on the structure of the cluster, involving significant charge transfer and formation of an incipient chemical Si–Xe bond with De = 0.3 eV.

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Language(s): eng - English
 Dates: 2012-11-202012-12-092012-12-192013-02-05
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/j.cplett.2012.12.020
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Title: Chemical Physics Letters
  Other : Chem. Phys. Lett.
Source Genre: Journal
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Publ. Info: Amsterdam : North-Holland
Pages: - Volume / Issue: 557 Sequence Number: - Start / End Page: 49 - 52 Identifier: ISSN: 0009-2614
CoNE: https://pure.mpg.de/cone/journals/resource/954925389241