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  METAL-GRAPHITE REAGENTS IN CARBOHYDRATE CHEMISTRY. VII. FRAGMENTATION OF O-ALKYLIDENE-DEOXY HALO SUGARS

Fürstner, A., Koglbauer, U., & Weidmann, H. (1990). METAL-GRAPHITE REAGENTS IN CARBOHYDRATE CHEMISTRY. VII. FRAGMENTATION OF O-ALKYLIDENE-DEOXY HALO SUGARS. Journal of Carbohydrate Chemistry, 9(5), 561-570. doi:10.1080/07328309008543853.

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 Creators:
Fürstner, Alois1, Author           
Koglbauer, Ulrike1, Author
Weidmann, Hans1, Author
Affiliations:
1Institute of Organic Chemistry, Technical University Graz, ou_persistent22              

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Free keywords: Carbohydrates
 Abstract: Contrary to the methods previously described, treatment with zinc/- silver-graphite or potassium-graphite laminate (CsK) of the di-0- isopropylidene derivatives of 1-deoxy-l-halo-[beta]-D-fructopyranose, 1-deoxy- 1-halo-[alpha]-L-sorbofuranose, 6-deoxy-6-iodo-[alpha]-D-galactopyranose, and 3- deoxy-3-iodo-[alpha]-D-glucofuranose resulted in the high yield formation of the respective unsaturated sugar derivatives by fragmentation with loss of one of the acetal groups.

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Language(s): eng - English
 Dates: 1990-03-201989-09-041990
 Publication Status: Issued
 Pages: 10
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1080/07328309008543853
 Degree: -

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Title: Journal of Carbohydrate Chemistry
Source Genre: Journal
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Publ. Info: New York : Marcel Dekker, Inc.
Pages: 10 Volume / Issue: 9 (5) Sequence Number: - Start / End Page: 561 - 570 Identifier: ISSN: 0732-8303
DOI: 10.1080/07328309008543853