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  Metal-Free Hydrogenation of Electron-Poor Allenes and Alkenes

Inés, B., Palomas Dona, D., Holle, S., Steinberg, S., Nicasio Collazo, J. A., & Alcarazo, M. (2012). Metal-Free Hydrogenation of Electron-Poor Allenes and Alkenes. Angewandte Chemie International Edition: a journal of the Gesellschaft Deutscher Chemiker, 51(49), 12367-12369. doi:10.1002/anie.201205348.

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 Creators:
Inés, B.1, Author           
Palomas Dona, David1, Author           
Holle, Sigrid1, Author           
Steinberg, Sebastian1, Author           
Nicasio Collazo, Juan Antonio1, Author           
Alcarazo, M.1, Author           
Affiliations:
1Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445592              

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Free keywords: alkylidene malonates allenes frustrated Lewis pairs metal-free hydrogenation
 Abstract: The poorer, the better: A metal-free catalytic procedure for the reduction of electron-poor allenes and alkenes has been developed. The method employs a frustrated Lewis pair based catalyst. 1,4-Diazabicyclo[2.2.2]octane (DABCO)/B(C6F5)3 was shown to be the best combination in optimization studies.

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Language(s): eng - English
 Dates: 2012-11-042012-12-03
 Publication Status: Issued
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201205348
 Degree: -

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Title: Angewandte Chemie International Edition : a journal of the Gesellschaft Deutscher Chemiker
Source Genre: Journal
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Publ. Info: Weinheim/Bergstr. : Verlag Chemie
Pages: 3 Volume / Issue: 51 (49) Sequence Number: - Start / End Page: 12367 - 12369 Identifier: ISSN: 0570-0833
CoNE: https://pure.mpg.de/cone/journals/resource/110984073528720
DOI: 10.1002/anie.201205348