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  Photoexcitation of mass/charge selected hemin⁺, caught in helium nanodroplets

Filsinger, F., Ahn, D.-S., Meijer, G., & Helden, G. v. (2012). Photoexcitation of mass/charge selected hemin⁺, caught in helium nanodroplets. Physical Chemistry Chemical Physics, 14(38), 13370-13377. doi:10.1039/c2cp42071f.

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Filsinger, Frank1, Autor           
Ahn, Doo-Sik1, Autor           
Meijer, Gerard1, Autor           
Helden, Gert von1, Autor           
Affiliations:
1Molecular Physics, Fritz Haber Institute, Max Planck Society, ou_634545              

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 Zusammenfassung: We report on a method by which mass/charge selected ions are picked up from a linear ion trap by liquid helium droplets. The size distributions of the doped droplets are measured via acceleration experiments. Depending on the source temperature, droplet sizes ranging from tens of thousands to several million helium atoms are obtained. Droplets doped with hemin, an iron containing porphyrin molecule, in the charge state +1 are then investigated using laser spectroscopy. It is observed that excitation with UV/VIS light can lead to ejection of the ion from the droplet. For doped droplets with a median size of B150 000 helium atoms, the absorption of two photons at 380 nm is needed for ejection to become efficient. When droplets become smaller, the ejection efficiency is observed to strongly increase. Monitoring the ejection yield as a function of excitation wavelength can be used to obtain the optical spectrum of hemin⁺. Compared to the spectrum of free gas-phase hemin⁺ at room temperature, the narrower and shifted to the blue.

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Sprache(n): eng - English
 Datum: 2012-06-202012-08-092012-08-092012
 Publikationsstatus: Erschienen
 Seiten: 8
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: Expertenbegutachtung
 Identifikatoren: DOI: 10.1039/c2cp42071f
 Art des Abschluß: -

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Titel: Physical Chemistry Chemical Physics
Genre der Quelle: Zeitschrift
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Ort, Verlag, Ausgabe: Cambridge [England] : Royal Society of Chemistry
Seiten: - Band / Heft: 14 (38) Artikelnummer: - Start- / Endseite: 13370 - 13377 Identifikator: ISSN: 1463-9076
CoNE: https://pure.mpg.de/cone/journals/resource/954925272413_1