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  Spirocyclopropane-type sesquiterpene hydrocarbons from Schinus terebinthifolius Raddi

Richter, R., von Reuß, S. H., & König, W. A. (2010). Spirocyclopropane-type sesquiterpene hydrocarbons from Schinus terebinthifolius Raddi. Phytochemistry, 71(11-12), 1371-1374. doi:10.1016/j.phytochem.2010.05.003.

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EXT073.pdf (Publisher version), 210KB
 
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Richter, Rita, Author
von Reuß, Stephan H.1, Author           
König, Wilfried A., Author
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Free keywords: Schinus terebinthifolius; Anacardiaceae; Sesquiterpene hydrocarbons; Spirocyclopropane; Terebinthane; Terebanene; Teredenene; Terebinthene
 Abstract: The essential oil of Schinus terebinthifolius fruits was reinvestigated using GC and GC-MS techniques. Apart from several known compounds three sesquiterpene hydrocarbons with a carbon skeleton exhibiting the rare spiro(cyclopropane) moiety could be isolated by a combination of column chromatography and GLC. Structure assignments were carried out by NMR spectroscopy. These natural products are 9-spiro(cyclopropa)-4,4,8-trimethyl-2-methylenbicyclo[4.3.0]non-1(6)-ene (terepanene), 9-spiro(cyclopropa)-2,4,4,8-tetramethylbicyclo[4.3.0]nona-1,5-diene (teredenene), and (6R*,8R*)-9-spiro(cyclopropa)-2,4,4,8-tetramethylbicyclo[4.3.0]non-1-ene (terebinthene). (C) 2010 Elsevier Ltd. All rights reserved.

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 Dates: 2010
 Publication Status: Issued
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 Identifiers: Other: EXT073
DOI: 10.1016/j.phytochem.2010.05.003
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Title: Phytochemistry
  Other : Phyto
Source Genre: Journal
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Publ. Info: Oxford : Pergamon
Pages: - Volume / Issue: 71 (11-12) Sequence Number: - Start / End Page: 1371 - 1374 Identifier: ISSN: 0031-9422
CoNE: https://pure.mpg.de/cone/journals/resource/954925433416