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  Study concerning the effects of chelation on the structure and catalytic activity of ruthenium carbene complexes

Fürstner, A., Thiel, O. R., & Lehmann, C. W. (2002). Study concerning the effects of chelation on the structure and catalytic activity of ruthenium carbene complexes. Organometallics, 21(2), 331-335. doi:10.1021/om0108503.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000F-9A29-8 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-001A-2A8D-4
Genre: Journal Article

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 Creators:
Fürstner, A.1, Author           
Thiel, O. R.1, Author           
Lehmann, C. W.2, Author           
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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 Abstract: The ruthenium chelate complexes 4 and 5 were prepared by reaction of the Grubbs catalyst 1 and its second-generation analogue 2 with the 2-vinylbenzoic acid isopropyl ester 3 in the presence of CuCl. The fact that the chelating carbonyl group in these complexes attenuates their catalytic activity sets an experimental basis for the interpretation of reactivity data previously described in the literature.

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Language(s): eng - English
 Dates: 2002-01-21
 Publication Status: Issued
 Pages: -
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 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 20173
DOI: 10.1021/om0108503
ISI: 000173405600013
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Title: Organometallics
  Alternative Title : Organometallics
Source Genre: Journal
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Pages: - Volume / Issue: 21 (2) Sequence Number: - Start / End Page: 331 - 335 Identifier: ISSN: 0276-7333