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  Chasing a Phantom by Total Synthesis: The Butylcycloheptylprodigiosin Case

Fürstner, A., Radkowski, K., & Peters, H. (2005). Chasing a Phantom by Total Synthesis: The Butylcycloheptylprodigiosin Case. Angewandte Chemie International Edition, 44(18), 2777-2781. doi:10.1002/anie.200462215.

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 Creators:
Fürstner, Alois1, Author           
Radkowski, Karin1, Author           
Peters, Hartwig1, Author           
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              

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Free keywords: alkaloids; cyclophanes; medium-ring compounds; palladium; pyrroles
 Abstract: The dispute as to whether “butylcycloheptylprodigiosin” is a natural product or solely a misassigned structure lasted for more than a decade. This open question has now been answered by the first total synthesis of this tripyrrole alkaloid, which makes explicit use of the peculiarities of its highly strained ortho-anellated nine-membered ring.

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Language(s): eng - English
 Dates: 2005-10-062005-03-302005-04-29
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 265291
DOI: 10.1002/anie.200462215
ISI: 000228957600027
 Degree: -

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Title: Angewandte Chemie International Edition
  Other : Angew. Chem. Int. Ed.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim : Wiley-VCH Verlag GmbH & Co. KGaA
Pages: - Volume / Issue: 44 (18) Sequence Number: - Start / End Page: 2777 - 2781 Identifier: ISSN: 1521-3773
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833