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  Preparation of oriented liquid-crystalline/isotropic block copolymer films with parallel or perpendicular arrangement of smectic layers and lamellar microdomains

Figueiredo, P., Gronski, W., & Bach, M. (2002). Preparation of oriented liquid-crystalline/isotropic block copolymer films with parallel or perpendicular arrangement of smectic layers and lamellar microdomains. Macromolecular Rapid Communications, 23(1), 38-43.

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 Creators:
Figueiredo, P., Author
Gronski, W.1, Author           
Bach, M.1, Author           
Affiliations:
1MPI for Polymer Research, Max Planck Society, ou_1309545              

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Free keywords: block copolymers; liquid-crystalline polymers (L;C); morphology; orientation
 Abstract: Communication: Films of a symmetric liquid- crystalline/isotropic block copolymer consisting of a smectic LC side-chain polymer and polystyrene were prepared by solvent casting from solution and from the isotropic melt. By annealing the solvent-cast film in the S-A phase an oriented microphase- separated film of lamellar morphology was obtained in which both the lamellae of the block copolymer and the smectic layers of the LC block were oriented parallel to the film surface. A lamellar morphology with perpendicular orientation of lamellae and smectic layers was generated by cooling the block copolymer from the melt.

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Language(s): eng - English
 Dates: 2002-01-09
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: No review
 Identifiers: eDoc: 28556
ISI: 000173614800007
 Degree: -

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Title: Macromolecular Rapid Communications
  Alternative Title : Macromol. Rapid Commun.
Source Genre: Journal
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Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 23 (1) Sequence Number: - Start / End Page: 38 - 43 Identifier: ISSN: 1022-1336