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  Photosensitive mesoionic main-chain polymers: Synthesis and anisotropic changes of the refractive index on irradiation of spin-coated films

Theis, A., Ritter, H., Böhme, F., Klinger, C., Mittler, S., & Menges, B. (2002). Photosensitive mesoionic main-chain polymers: Synthesis and anisotropic changes of the refractive index on irradiation of spin-coated films. Chemistry of Materials, 14(5), 2109-2112.

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 Creators:
Theis, A.1, Author           
Ritter, H., Author
Böhme, F., Author
Klinger, C., Author
Mittler, Silvia1, Author           
Menges, B.1, Author           
Affiliations:
1MPI for Polymer Research, Max Planck Society, ou_1309545              

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 Abstract: A polymeric amidine prepared by melt condensation was converted to a photosensitive polymesoion by a polymer analogous condensation reaction with methylmalonic acid. The polymeric mesoion was characterized by NMR, IR, and UV spectroscopies; SEC; and DSC. For investigation of optical properties, spin- coated films were prepared and analyzed by waveguide spectroscopy. It was found that the refractive index shows anisotropic changes and that the film thickness was reduced upon irradiation as a result of conversion to a polybis(beta- lactame) structure.

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Language(s): eng - English
 Dates: 2002-05
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: No review
 Identifiers: eDoc: 28484
ISI: 000175790100029
Other: P-02-57
 Degree: -

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Title: Chemistry of Materials
  Alternative Title : Chem. Mat.
Source Genre: Journal
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Publ. Info: -
Pages: - Volume / Issue: 14 (5) Sequence Number: - Start / End Page: 2109 - 2112 Identifier: ISSN: 0897-4756