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  Synthesis and photomodulation of rigid polyphenylene dendrimers with an azobenzene core

Grebel-Koehler, D., Liu, D. J., De Feyter, S., Enkelmann, V., Weil, T., Engels, C., et al. (2003). Synthesis and photomodulation of rigid polyphenylene dendrimers with an azobenzene core. Macromolecules, 36(3), 578-590.

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 Creators:
Grebel-Koehler, D.1, Author           
Liu, D. J., Author
De Feyter, S., Author
Enkelmann, Volker1, Author           
Weil, T., Author
Engels, C., Author
Samyn, C., Author
Müllen, Klaus1, Author           
De Schryver, F. C., Author
Affiliations:
1MPI for Polymer Research, Max Planck Society, ou_1309545              

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 Abstract: A series of azobenzene-cored polyphenylene dendrimers have been synthesized. The photoresponsive properties of these dendrimers have been investigated by optical spectroscopy and gel permeation chromatography (GPC). These polyphenylene dendrimers exhibit a photoresponsive behavior upon UV and visible irradiation, resulting in a reversible and appreciable change of the dendrimer structure. Furthermore, the influence of dendrimer generation and degree of branching on the kinetic characteristics of the photoisomerization is discussed. The crystal structures of two precursors and two solvate structures of the first generation are presented.

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Language(s): eng - English
 Dates: 2003-02-11
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: eDoc: 28408
ISI: 000180868000014
Other: P-03-160
 Degree: -

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Title: Macromolecules
  Alternative Title : Macromolecules
Source Genre: Journal
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Publ. Info: -
Pages: - Volume / Issue: 36 (3) Sequence Number: - Start / End Page: 578 - 590 Identifier: ISSN: 0024-9297