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  Stabilization of 200-Atom Platinum Nanoparticles by Organosilane Fragments

Pelzer, K., Hävecker, M., Boualleg, M., Candy, J.-P., & Basset, J.-M. (2011). Stabilization of 200-Atom Platinum Nanoparticles by Organosilane Fragments. Angewandte Chemie International Edition: a journal of the Gesellschaft Deutscher Chemiker, 50(22), 5170-5173. doi:10.1002/anie.201008209.

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1310621.pdf (Any fulltext), 1022KB
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2011
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 Creators:
Pelzer, Katrin1, Author           
Hävecker, Michael1, Author           
Boualleg, Malika2, Author
Candy, Jean-Pierre2, Author
Basset, Jean-Marie2, Author
Affiliations:
1Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              
2C2P2-LCOMS, UMR CNRS-CPE 5265, Villeurbanne (France), ou_persistent22              

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Free keywords: heterogeneous catalysis; nanoparticles; platinum
 Abstract: Three's a charm: Platinum nanoparticles of 2 nm diameter and containing approximately 200 atoms covered with n-octylsilyl groups (see picture, right; Pt blue, Si red, C gray, H turquoise) form when [Pt(dba)2] (dba=dibenzylideneacetone) decomposes in the presence of n-octylsilane. The particles adopt a cuboctahedral structure with an edge length of three atoms.

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Language(s): eng - English
 Dates: 2011-04-192011-05-23
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201008209
 Degree: -

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Title: Angewandte Chemie International Edition : a journal of the Gesellschaft Deutscher Chemiker
Source Genre: Journal
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Publ. Info: Weinheim/Bergstr. : Verlag Chemie
Pages: - Volume / Issue: 50 (22) Sequence Number: - Start / End Page: 5170 - 5173 Identifier: ISSN: 0570-0833
CoNE: https://pure.mpg.de/cone/journals/resource/110984073528720