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Free keywords:
Asymmetric reduction of (e)-alk-2-enoates
Chirally deuterated sphingosines
Chirally deuterated palmitic acid
Cuprate mediated alkylation
Oxidations
Wittig reactions
Lipids.
D-erythro-sphingosine
Sex-pheromone
Fatty-acids
Threo-sphingosine
Biosynthesis
Desaturase
Identification
Lepidoptera
Sphingolipids
Saturniidae.
Chemistry & Analysis in Current Contents(R)/Life Sciences. Organic Chemistry/Polymer Science in Current Contents(R)/Physical, Chemical & Earth Sciences.
Abstract:
The stereospecifically labelled (6R,7R)-[4,5,6,7-H-2(4)]-palmitic acid (14) and (8S,9R)-[8,9-H-2(2)]-L-erythro-sphinganine (10) have been prepared in good yield from (E)-[2,3-H-2(2)]-dodec-2-enoate 5 via biocatalytic reduction with broken cells of Clost