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  Structural evolution of aragonite superstructures obtained in the presence of the siderophore deferoxamine

Willinger, M. G., Polleux, J., Antonietti, M., Cölfen, H., Pinna, N., & Nassif, N. (2015). Structural evolution of aragonite superstructures obtained in the presence of the siderophore deferoxamine. CrystEngComm, 17(21), 3927-3935. doi:10.1039/C5CE00186B.

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c5ce00186b.pdf (Publisher version), 6MB
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 Creators:
Willinger, Marc Georg1, Author           
Polleux, J.2, Author           
Antonietti, Markus3, Author           
Cölfen, H.2, 4, Author           
Pinna, Nicola5, Author
Nassif, N.2, 6, Author           
Affiliations:
1Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              
2Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863288              
3Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863321              
4Universität Konstanz, Physikalische Chemie, Universitätsstr. 10, D-78457 Konstanz, Germany , ou_persistent22              
5Humboldt-Universität zu Berlin, Institut für Chemie, Brook-Taylor-Str. 2, 12489 Berlin, Germany , ou_persistent22              
6Laboratoire Chimie de la Matière Condensée de Paris, UMR 7574 CNRS, UPMC, Collège de France, 11 place Marcellin Berthelot, 75231 Paris Cedex 05, France , ou_persistent22              

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 Abstract: The effect of amphoteric siderophore deferoxamine on the crystallization behavior of calcium carbonate was investigated under bioinspired conditions. Amphoteric siderophore deferoxamine possesses self-organization ability, surface activity and ion-chelating properties. It induces in the present case the formation of unusual, highly organized aragonite mesocrystals during the precipitation of calcium carbonate from liquid phase. A detailed investigation of the structure and growth of the particles provides an insight into the role of the deferoxamine and its function in the crystallization process.

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Language(s): eng - English
 Dates: 2015-01-272015-03-092015-03-092015-06-07
 Publication Status: Issued
 Pages: 9
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/C5CE00186B
 Degree: -

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Title: CrystEngComm
  Other : CrystEngComm
Source Genre: Journal
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Publ. Info: London : Royal Society of Chemistry
Pages: - Volume / Issue: 17 (21) Sequence Number: - Start / End Page: 3927 - 3935 Identifier: ISSN: 1466-8033
CoNE: https://pure.mpg.de/cone/journals/resource/954928434986