非表示:
キーワード:
macrolides;
metathesis;
natural products;
ruthenium;
total synthesis;
zinc
要旨:
Organometallic chemistry in general and catalysis in particular are used in the first total synthesis of amphidinolide T4 (see scheme); a prototype member of a series of macrolide antibiotics of marine origin with rings containing an odd number of carbon atoms.
