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  Synthesis and X-ray structures of tetralithium derivatives of tert-butylcalix[4]arene containing unique Li–O cores basedon a square-pyramidal geometry

Davidson, M. G., Howard, J. A. K., Lamb, S., & Lehmann, C. W. (1997). Synthesis and X-ray structures of tetralithium derivatives of tert-butylcalix[4]arene containing unique Li–O cores basedon a square-pyramidal geometry. Chemical Communications, 1997(17), 1607-1608. doi:10.1039/A702280H.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0024-76AA-7 Version Permalink: https://hdl.handle.net/21.11116/0000-000D-ABBB-0
Genre: Journal Article

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 Creators:
Davidson, Matthew G.1, Author
Howard, Judith A. K.1, Author
Lamb, Sarah1, Author
Lehmann, Christian W.1, Author           
Affiliations:
1Department of Chemistry, University of Durham, South Road, Durham, DH1 3LE, UK, ou_persistent22              

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 Abstract: Tetralithiation of tert-butylcalix[4]arene in the presence of hmpa (hexamethylphosphoramide) results in the isolation of either a monomeric complex in which LiOH is incorporated into an Li5O5 core based on an isolated square pyramid of Li atoms, or a dimeric LiOH-free species containing an Li8O8 core in which the same structural motif is maintained by edge-sharing of two square pyramids of Li atoms.

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Language(s): eng - English
 Dates: 1997-09-07
 Publication Status: Issued
 Pages: 2
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/A702280H
 Degree: -

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Title: Chemical Communications
  Other : Chem. Commun.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 1997 (17) Sequence Number: - Start / End Page: 1607 - 1608 Identifier: ISSN: 1359-7345
CoNE: https://pure.mpg.de/cone/journals/resource/954928495413