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  An (e, 2e + ion) study of low-energy electron-impact ionization and fragmentation of tetrahydrofuran with high mass and energy resolutions

Ren, X. G., Pflüger, T., Weyland, M., Baek, W. Y., Rabus, H., Ullrich, J., et al. (2014). An (e, 2e + ion) study of low-energy electron-impact ionization and fragmentation of tetrahydrofuran with high mass and energy resolutions. The Journal of Chemical Physics, 141(13): 134314. doi:10.1063/1.4896614.

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http://dx.doi.org/10.1063/1.4896614 (Verlagsversion)
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 Urheber:
Ren, X. G.1, 2, Autor           
Pflüger, Thomas1, 2, Autor           
Weyland, Marvin1, 2, Autor           
Baek, Woon Yoon2, Autor
Rabus, Hans2, Autor
Ullrich, Joachim2, Autor
Dorn, Alexander1, Autor           
Affiliations:
1Division Prof. Dr. Thomas Pfeifer, MPI for Nuclear Physics, Max Planck Society, ou_2025284              
2Physikalisch-Technische Bundesanstalt, 38116 Braunschweig, Germany, ou_persistent22              

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 Zusammenfassung: We study the low-energy (E 0 = 26 eV) electron-impact induced ionization and fragmentation of tetrahydrofuran using a reaction microscope. All three final-state charged particles, i.e., two outgoing electrons and one fragment ion, are detected in triple coincidence such that the momentum vectors and, consequently, the kinetic energies for charged reaction products are determined. The ionic fragments are clearly identified in the experiment with a mass resolution of 1 amu. The fragmentation pathways of tetrahydrofuran are investigated by measuring the ion kinetic energy spectra and the binding energy spectra where an energy resolution of 1.5 eV has been achieved using the recently developed photoemission electron source. Here, we will discuss the fragmentation reactions for the cations C4H8O+, C4H7O+, C2H3O+, C3H+6 , C3H+5 , C3H+3 , CH3O+, CHO+, and C2H+3 .

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Sprache(n): eng - English
 Datum: 2014-10-07
 Publikationsstatus: Online veröffentlicht
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 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: Expertenbegutachtung
 Identifikatoren: DOI: 10.1063/1.4896614
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Titel: The Journal of Chemical Physics
Genre der Quelle: Zeitschrift
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Ort, Verlag, Ausgabe: -
Seiten: - Band / Heft: 141 (13) Artikelnummer: 134314 Start- / Endseite: - Identifikator: ISSN: 1520-9032
CoNE: https://pure.mpg.de/cone/journals/resource/991042752807952