ausblenden:
Schlagwörter:
Acyclische Carbene; Gold; Ligandendesign; Transmetallierungen; Ylide
Zusammenfassung:
No cycle required: The straightforward synthesis of acyclic (amino)(ylide)carbene gold complexes was achieved by reaction of isocyanide gold complexes with phosphorus and arsenic ylides as well as electron-rich olefins. Their ability to form bimetallic species and to act as ligand-transfer reagents has also been established.
