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  Synthesis of hydroquinone-, biphenol-, and binaphthol-containing aza macroheterocycles via regioselective hydroformylation and reductive amination

Angelovski, G., & Eilbracht, P. (2003). Synthesis of hydroquinone-, biphenol-, and binaphthol-containing aza macroheterocycles via regioselective hydroformylation and reductive amination. Tetrahedron, 59(41), 8265-8274. doi:10.1016/j.tet.2003.08.012.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0013-DD86-3 Version Permalink: https://hdl.handle.net/21.11116/0000-0004-6F16-8
Genre: Journal Article

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https://www.sciencedirect.com/science/article/pii/S004040200301250X (Publisher version)
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 Creators:
Angelovski, G1, Author           
Eilbracht, P, Author
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1External Organizations, ou_persistent22              

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 Abstract: Rhodium(I) catalyzed regioselective hydroformylation of diolefins and
subsequent reductive amination of the dialdehydes in the presence of
α,ω-diamines is applied to azamacroheterocyclic ring synthesis











Rhodium(I) catalyzed regioselective
hydroformylation of diolefins and subsequent reductive amination of the
dialdehydes in the presence of α,ω-diamines is applied to
azamacroheterocyclic ring synthesis. Starting from aromatic diallyl ethers of
hydroquinone, biphenol and binaphthol 20–28 membered macroheterocycles were
obtained in up to 78 yield.

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 Dates: 2003-10
 Publication Status: Issued
 Pages: -
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 Table of Contents: -
 Rev. Type: -
 Identifiers: BibTex Citekey: 3242
DOI: 10.1016/j.tet.2003.08.012
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Title: Tetrahedron
  Other : Tetrahedron : the international journal for the rapid publication of full original research papers and critical reviews in organic chemistry
Source Genre: Journal
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Publ. Info: Kidlington : Elsevier Science
Pages: - Volume / Issue: 59 (41) Sequence Number: - Start / End Page: 8265 - 8274 Identifier: ISSN: 0040-4020
CoNE: https://pure.mpg.de/cone/journals/resource/00404020