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キーワード:
-
要旨:
Rhodium(I) catalyzed regioselective hydroformylation of diolefins and
subsequent reductive amination of the dialdehydes in the presence of
α,ω-diamines is applied to azamacroheterocyclic ring synthesis
Rhodium(I) catalyzed regioselective
hydroformylation of diolefins and subsequent reductive amination of the
dialdehydes in the presence of α,ω-diamines is applied to
azamacroheterocyclic ring synthesis. Starting from aromatic diallyl ethers of
hydroquinone, biphenol and binaphthol 2028 membered macroheterocycles were
obtained in up to 78 yield.
