非表示:
キーワード:
Coupling reaction
Crystal structure
Cycloaddition reaction
Substituent effects
Zwitterions
要旨:
The synthesis of several electron poor allenes bearing electron withdrawing substituents is described and their use as Lewis acids in the field of frustrated Lewis pair (FLP) chemistry reported. At room
temperature the combination of N-heterocyclic carbenes (NHC) with the allenes under study invariably
afforded the corresponding Lewis adducts; however, at −78 °C this reaction is in most of the cases inhibited and kinetically induced organic FLPs are formed. Under these conditions the activation of S–S
bonds in disulfides has been achieved in excellent yields.
