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  A new method to synthesize very active and stable supported metal Pt catalysts: thermo-destabilization of microemulsions

Parapat, R. Y., Parwoto, V., Schwarze, M., Zhang, B. S., Su, D. S., & Schomäcker, R. (2012). A new method to synthesize very active and stable supported metal Pt catalysts: thermo-destabilization of microemulsions. Journal of Materials Chemistry, 22(23), 11605-11614. doi:10.1039/c2jm15468d.

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c2jm15468d.pdf (Publisher version), 2MB
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 Creators:
Parapat, Riny Y.1, Author
Parwoto, Veronica1, Author
Schwarze, Micheal1, Author
Zhang, Bing Sen2, Author           
Su, Dang Sheng2, Author           
Schomäcker, Reinhard1, Author
Affiliations:
1Technische Universität Berlin, Strasse des 17. Juni 124, 10623 Berlin, Germany, ou_persistent22              
2Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              

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 Abstract: A new technique to deposit nanoparticles synthesized in reverse micellar microemulsions onto support material without agglomeration is named thermal destabilization of microemulsion. The multifaceted Pt crystals, mostly truncated octahedra, were produced inside reverse micelles with an average size of 2.5 nm and a narrow size distribution. After deposition, the Pt crystals were found to be well dispersed on the support with an average size of 2.5 nm. After testing with hydrogenation of α-methyl styrene, the produced Pt-catalyst showed higher activity (6 times higher) and stability than commercial ones. The advantages of this synthesis route of nanoparticles include simple operation, and the ease of controlling the size and shape of nanoparticles without using capping agents.

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Language(s): eng - English
 Dates: 2011-10-262012-03-302012-05-042012-06-21
 Publication Status: Issued
 Pages: -
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 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/c2jm15468d
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Title: Journal of Materials Chemistry
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 22 (23) Sequence Number: - Start / End Page: 11605 - 11614 Identifier: ISSN: 0959-9428
CoNE: https://pure.mpg.de/cone/journals/resource/954925273429