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Abstract:
Redox reaction between [(phen)4Fe2(Cl)2(μ-O)]Cl2·4.5H2O (phen = 1,10-phenanthroline) and Mn(OH)2·xH2O in water methanol solution at refluxing temperature under inert atmosphere gives a novel low-spin iron(II)–oxo complex [(phen)4Fe2(Cl)2(μ-O)]·4H2O (1) which has been characterised by IR, Mössbauer, electrochemical and magnetic studies. The crystal structure shows that complex 1 is a dinuclear single oxo-bridged Fe(II) species with distorted octahedral geometry.
