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  Practical Synthesis of (E)‐α,β‐Unsaturated Esters from Aldehydes

List, B., Döhring, A., Hechavarria Fonseca, M. T., Wobser, K., van Thienen, H., Rios Torres, R., et al. (2005). Practical Synthesis of (E)‐α,β‐Unsaturated Esters from Aldehydes. Advanced Synthesis & Catalysis, 347(11-13), 1558-1560. doi:10.1002/adsc.200505196.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000F-9585-2 Version Permalink: https://hdl.handle.net/21.11116/0000-0008-3CE6-2
Genre: Journal Article

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 Creators:
List, Benjamin1, Author           
Döhring, Arno1, Author           
Hechavarria Fonseca, Maria T.1, Author           
Wobser, Kathrin1, Author           
van Thienen, Hendrik1, Author           
Rios Torres, Ramon1, Author           
Llamas Galilea, Pedro1, Author           
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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Free keywords: atom economy; Doebner-Knoevenagel reaction; malonic acid half esters; (E)-stereoselectivity; α,β-unsaturated esters
 Abstract: Based on a modification of the Doebner–Knoevenagel reaction, a practical and highly efficient synthesis of α,β‐unsaturated esters with excellent regio‐ and stereoselectivity was developed. The reactions are catalyzed by 4‐dimethylaminopyridine in DMF at room temperature or below. Both aliphatic and aromatic aldehydes can readily be used in the process.

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Language(s): eng - English
 Dates: 2005-05-132005-07-272005-10-19
 Publication Status: Issued
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/adsc.200505196
 Degree: -

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Title: Advanced Synthesis & Catalysis
  Abbreviation : Adv. Synth. Catal.
Source Genre: Journal
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Publ. Info: Weinheim, Fed. Rep. of Germany : Wiley-VCH Verlag GmbH
Pages: - Volume / Issue: 347 (11-13) Sequence Number: - Start / End Page: 1558 - 1560 Identifier: ISSN: 1615-4150
CoNE: https://pure.mpg.de/cone/journals/resource/958634688013