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  Asymmetric Counteranion-Directed Transition-Metal Catalysis: Enantioselective Epoxidation of Alkenes with Manganese(III) Salen Phosphate Complexes

Liao, S., & List, B. (2010). Asymmetric Counteranion-Directed Transition-Metal Catalysis: Enantioselective Epoxidation of Alkenes with Manganese(III) Salen Phosphate Complexes. Angewandte Chemie International Edition, 49(3), 628-631. doi:10.1002/anie.200905332.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000F-8DB3-E Version Permalink: https://hdl.handle.net/21.11116/0000-0008-480A-D
Genre: Journal Article

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 Creators:
Liao, Saihu1, Author           
List, Benjamin1, Author           
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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Free keywords: ACDC; alkenes; asymmetric epoxidation; chiral counteranions; phosphates
 Abstract: Paired up: A highly active and enantioselective ion‐pair epoxidation catalyst, consisting of an achiral MnIII–salen complex and a chiral phosphate counteranion, mediates the epoxidization of a wide range of alkenes with high yields and enantioselectivities (see scheme). The unique role of the counteranion is to stabilize an enantiomorphic conformation of the cationic Mn catalyst.

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Language(s): eng - English
 Dates: 2009-09-232010-01-072010-01-12
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.200905332
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 49 (3) Sequence Number: - Start / End Page: 628 - 631 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851