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  Comparative study of the NMR length scale of dynamic heterogeneities of three different glass formers

Reinsberg, S. A., Heuer, A., Doliwa, B., Zimmermann, H., & Spiess, H. W. (2002). Comparative study of the NMR length scale of dynamic heterogeneities of three different glass formers. Journal of Non-Crystalline Solids, 307, 208-214. doi:10.1016/S0022-3093(02)01460-6.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000F-650B-A Version Permalink: https://hdl.handle.net/21.11116/0000-0002-7A09-C
Genre: Journal Article

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 Creators:
Reinsberg, S. A.1, Author           
Heuer, Andreas2, Author           
Doliwa, B.1, Author           
Zimmermann, H., Author
Spiess, Hans Wolfgang1, Author           
Affiliations:
1MPI for Polymer Research, Max Planck Society, ou_1309545              
2Univ Münster, Inst Phys Chem, D-48149 Münster, Germany, ou_persistent22              

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 Abstract: This article presents a comparison of the determination of the length scale of dynamic heterogeneities in different glass formers by means of a multidimensional C-13 solid-state exchange NMR experiment. So far, results for poly(vinyl acetate) and glycerol have been reported. The existing data together with new results for o-terphenyl have been reanalysed in a slightly revised procedure. This revision is rationalised by computer experiments which are performed on hard-sphere systems in analogy to the NMR experiment. While we find domains in the region of 2-4 nm for PVAc and o-terphenyl, glycerol has a smaller domain of approximate to1 nm. (C) 2002 Elsevier Science B.V. All rights reserved.

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Language(s): eng - English
 Dates: 2002-09
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: No review
 Identifiers: eDoc: 28612
ISI: 000178038100029
Other: P-02-109
DOI: 10.1016/S0022-3093(02)01460-6
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Title: Journal of Non-Crystalline Solids
Source Genre: Journal
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Publ. Info: Amsterdam : North-Holland
Pages: - Volume / Issue: 307 Sequence Number: - Start / End Page: 208 - 214 Identifier: ISSN: 0022-3093
CoNE: https://pure.mpg.de/cone/journals/resource/954925416961